- Sand Gravel & Aggregate, Frederic
- Sandwich Shop Restaurants, Frederic
- Satellite Descrambling & Programming Service, Frederic
- Satellite Dish Antennas & Equipment Dealers, Frederic
- Satellite TV Service, Frederic
- Savings Banks, Frederic
- Scrap & Waste Materials, Frederic
- Scrapbooks Supplies Service & Instruction, Frederic
- Screen Printing, Frederic
- Secondary Schools, Frederic
- Senior Citizens Service & Health Organizations, Frederic
- Septic Tank Installation & Repair, Frederic - Septic Systems
- Septic Tank Pumping & Cleaning, Frederic - Septic Systems
- Septic Tanks & Septic Systems Contractors, Frederic - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
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- Sewer & Drain Cleaning & Repair, Frederic - Drain Cleaner & Installation Services
- Sewing & Yarn Stores & Supplies, Frederic
- Sharpening Service, Frederic
- Shopping & Shopping Services, Frederic
- Siding Contractors, Frederic - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Silos & Equipment, Frederic
- Snowmobile Repair, Parts, Sales & Service, Frederic
- Social Services & Welfare, Frederic
- Special Interest Schools Or Instruction, Frederic
- Specialty Animal Services, Frederic
- Specialty Stores, Frederic
- Sports & Recreational Services, Frederic
- State Government, Frederic
- Steel & Metal Goods, Frederic - Steel Distributors
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